Use the links below to access the publications - this is only available if you have a Web subscription to the appropriate journal. Otherwise, you may contact Pat Holland for reprints.
69. R. E. Cowley, N. A. Eckert, J. E. Elhaïk, P. L. Holland*, "Catalytic nitrene transfer from an imidoiron(III) complex to form carbodiimides and isocyanates," Chem. Commun. 2009, in press. (DOI)
68. D. J. Mindiola*, P. L. Holland*, T. H. Warren*, "Complexes of Bulky Beta-Diketiminate Ligands: Introduction," Inorg. Synth., in press.
67. M. S. Varonka, T. H. Warren*, T. R. Dugan, R. E. Cowley, P. L. Holland, "Beta-Diketiminate Precursors HLMe,Me3 and TlLMe,Me3,"Inorg. Synth., in press.
66. D. Adhikari, B. L. Tran, F. J. Zuno-Cruz, G. Sanchez Cabrera, D. J. Mindiola*, K. P. Chiang, R. E. Cowley, T. R. Dugan, P. L. Holland, "Beta-Diketiminate Precursors LMe,iPr2H, [LMe,iPr2Li]x, and [LtBu,iPr2K]x," Inorg. Synth., in press.
65. R. E. Cowley, K. P. Chiang, P. L. Holland*, D. Adhikari, F. J. Zuno-Cruz, G. Sanchez Cabrera, D. J. Mindiola, "Beta-Diketiminate Precursors LtBu,iPr2H and LtBu,iPr2Li(THF)," Inorg. Synth., in press.
64. B. D. Stubbert, P. L. Holland*, D. Adhikari, D. J. Mindiola, "Beta-Diketiminate Supported Iron Chloride Complex of LMe,iPr2," Inorg. Synth., in press.
63. K. P. Chiang, P. L. Holland*, D. Adhikari, D. J. Mindiola, "Beta-Diketiminate Supported Iron Chloride Complex of LtBu,iPr2," Inorg. Synth., in press.
62. K. Ding, P. L. Holland*, D. Adhikari, D. J. Mindiola, "Beta-Diketiminate Supported Cobalt Chloride Complex of LtBu,iPr2," Inorg. Synth., in press.
61. M. M. Melzer, E. Kogut, M. S. Varonka, S. Wiese, T. H. Warren*, S. S. Rocks, P. L. Holland, "Beta-Diketiminate Supported Nickel(II) and Nickel(I) Complexes of LMe,Me3," Inorg. Synth., in press.
60. T. R. Dugan, P. L. Holland*, S. Wiese, T. H. Warren, "Beta-Diketiminate Supported Nickel(II) Complex of LMe,iPr2," Inorg. Synth., in press.
59. Y. M. Badiei, T. H. Warren*, K. P. Chiang, P. L. Holland, "Beta-Diketiminate Supported Copper(I) Arene Complex of LMe,Me3," Inorg. Synth., in press.
58. P. L. Holland*, M. M. Melzer, T. H. Warren, "Beta-Diketiminate Supported Copper(II) Chloride Complex of LMe,iPr2, "Inorg. Synth., in press.
57. P. L. Holland, "Nitrogen Fixation," in McGraw-Hill Yearbook of Science & Technology, McGraw-Hill, New York, 2009, pp. 255-256. (book)
56. S. S. Rocks, W. W. Brennessel, T. E. Machonkin*, P. L. Holland*, "Solid-State and
Proton NMR Characterization of an Iron(II) Complex of a Tridentate, Facially Coordinating
N,N,O Donor Ligand," Inorg. Chim. Acta 2009, 362, 1387-1390. (DOI)
55. S. Stoian, J. M. Smith, P. L. Holland, E. Münck, E. L. Bominaar*, "Mössbauer, EPR, and theoretical study of a high-spin, four-coordinate Fe(II) diketiminate complex," Inorg Chem. 2008, 47, 8687-8695. (DOI)
54. P. L. Holland, "Electronic Structure
and Reactivity of Three-Coordinate Iron Complexes," Acc. Chem. Res. 2008, 41, 905-914. (DOI)
53. Y. Yu, A. R. Sadique, J. M. Smith, T. R. Dugan, R. E. Cowley, W. W. Brennessel, C. J. Flaschenriem, E. Bill, T. R. Cundari*, P. L. Holland*, "The Reactivity Patterns of Low-Coordinate Iron Hydride Complexes," J. Am. Chem. Soc. 2008, 130, 6624-6638. (DOI)
52. R. E. Cowley, J. Elhaik, N. A. Eckert, W. W. Brennessel, E. Bill*, P. L. Holland*, "A bridging hexazene (RNNNNNNR) ligand from reductive coupling of azides," J. Am. Chem. Soc. 2008, 130, 6074-6075. (DOI) (Highlight in Chemical & Engineering News)
51. A. R. Sadique, W. W. Brennessel, and P. L. Holland*, "Reduction of CO2 to CO Using
Low-Coordinate Iron: Formation of a Four-Coordinate Iron Dicarbonyl Complex and a Bridging Carbonate Complex," Inorg. Chem. 2008, 47, 784-786. (DOI)
50. N. S. Lees, R. L. McNaughton, W. V. Gregory, P.
L. Holland, and B. M. Hoffman*, "ENDOR Characterization of a Synthetic Diiron Hydrazido Complex as a
Model for Nitrogenase Intermediates," J. Am. Chem. Soc. 2008, 130, 546-555. (DOI)
49. A. R. Sadique, E. A. Gregory, W. W. Brennessel, P.
L. Holland*, "Mechanistic Insight into N=N Cleavage by a Low-Coordinate Iron(II)
Hydride Complex," J. Am. Chem. Soc. 2007, 129, 8112-8121. (DOI)
48. J. Vela, L. Zhu, C. J. Flaschenriem, W. W. Brennessel, R. J.
Lachicotte, P. L. Holland*, "Macrocyclic Binucleating β-Diketiminate Ligands
and their Lithium, Aluminum, and Zinc Complexes," Organometallics 2007, 26, 3416-3423. (DOI)
47. Y. Yu, W. W. Brennessel, P. L. Holland*, "Borane B-C Bond Cleavage by
a Low-Coordinate Iron Hydride Complex and N-N Bond Cleavage by the Hydridoborate Product,"
Organometallics 2007, 26, 3217-3226. (DOI)
46. J. Vela, J. Cirera, J. M. Smith, R. J. Lachicotte, C. J. Flaschenriem, S. Alvarez*, P. L. Holland*, "Quantitative Geometric Descriptions of the Belt Iron Atoms of the Iron-Molybdenum Cofactor of Nitrogenase and Synthetic Iron(II) Model Complexes," Inorg. Chem. 2007, 46, 60-71. (DOI)
45. N. A. Eckert, S. Vaddadi, S. Stoian, R. J.
Lachicotte, T. R. Cundari*, and P. L. Holland*, "Coordination Number Dependence of Reactivity
in an Imidoiron(III) Complex," Angew. Chem., Int. Ed. Engl. 2006, 45, 6868-6871. (online)
44. Travis J. Hebden, William W. Brennessel, Christine J. Flaschenriem, and Patrick L. Holland*,
"A dinucleating ligand related to the β-diketiminates,"Dalton Trans. 2006, 3855-3857. (DOI)
43. S. A. Stoian, J. Vela, J. M. Smith, A. R. Sadique, P. L. Holland, E. Münck*, E. L. Bominaar*, "Mössbauer and Computational Study of an N2-Bridged Diiron Diketiminate Complex: Parallel Alignment of the Iron Spins by Direct Antiferromagnetic Exchange with Activated Dinitrogen," J. Am. Chem. Soc. 2006, 128, 10181-10192. (DOI)
42. Y. Yu, J. M. Smith, C. J. Flaschenriem, P. L. Holland*, "Binding Affinity of Alkynes and Alkenes to Low-Coordinate Iron," Inorg. Chem. 2006, 45, 5742-5751. (DOI) (cover of Inorg. Chem.)
41. J. Vela, S. Vaddadi, S. Kingsley, C. J. Flaschenriem, R. J.
Lachicotte, T. R. Cundari*, P. L. Holland*, "Bidentate Coordination of Pyrazolate in Low-Coordinate Iron(II) and Nickel(II) Complexes," Angew. Chem., Int. Ed. Engl. 2006, 45, 1607-1611. (online)
40. J. M. Smith, A. R. Sadique, T. R. Cundari*, K. R. Rodgers*, G. Lukat-Rodgers, R. J. Lachicotte, C. J. Flaschenriem, J. Vela, and P. L. Holland*, "Studies of Low-Coordinate Iron Dinitrogen Complexes," J. Am. Chem. Soc. 2006, 128, 756-769. (DOI)
39. N. A. Eckert, A. Dinescu, T. R. Cundari*, P. L. Holland*, "A T-Shaped Three-Coordinate Nickel(I) Carbonyl Complex and the Geometric Preferences of Three-Coordinate d9 Complexes," Inorg. Chem. 2005, 44, 7702-7704. (DOI)
38. N. A. Eckert, S. Stoian, J. M. Smith, E. L. Bominaar*, E. Münck*, P. L. Holland*, "Synthesis, Structure, and Spectroscopy of an Oxodiiron(II) Complex," J. Am. Chem. Soc. 2005, 127, 9344-9345. (DOI)
37. S. Stoian, Y. Yu, J. M. Smith, P. L. Holland*, E. L.
Bominaar*, E. Münck*, "Mössbauer, EPR and Crystallographic
Characterization of a High-Spin Fe(I) Diketiminate Complex with Orbital
Degeneracy," Inorg. Chem. 2005, 44, 4915-4922. (DOI)
36. J. Vela, J. M. Smith, Y. Yu, N. A. Ketterer, C. J. Flaschenriem, R. J. Lachicotte, P. L. Holland*, "Synthesis and Reactivity of Low-Coordinate Iron(II) Fluoride Complexes and Their Use in the Catalytic Hydrodefluorination of Fluorocarbons," J. Am. Chem. Soc. 2005, 127, 7857-7870. (DOI)
35. E. A. Gregory, R. J. Lachicotte, P. L. Holland*, "A Cationic Three-Coordinate Iron(II) Complex and the Reaction of β-Diketiminate with Ethyl Diazoacetate," Organometallics 2005, 24, 1803-1805. (DOI)
34. P. L. Holland, "Low-Coordinate Iron Complexes as Synthetic Models of Nitrogenase," Can. J. Chem. 2005, 83, 296-301. (online)
33. J. Vela, S. Vaddadi, T. R. Cundari*, J. M. Smith, E. A. Gregory, R. J. Lachicotte, C. J. Flaschenriem, P. L. Holland*, "Reversible Beta-Hydrogen Elimination of Three-Coordinate Iron(II) Alkyl Complexes: Mechanistic and Thermodynamic Studies," Organometallics 2004, 23, 5226-5239. (DOI)
32. N. A. Eckert, J. M. Smith, R. J. Lachicotte, P. L. Holland*, "Low-coordinate Fe(II) Amido Complexes of β-Diketiminates: Synthesis, Structure and Reactivity," Inorg. Chem. 2004, 43, 3306-3321. (DOI)
31. J. Vela, S. Stoian, C. Flaschenriem, E.
Münck*, P. L. Holland*, "A Sulfido-Bridged Diiron(II) Compound and Its
Reactions with Nitrogenase-Relevant Substrates," J. Am. Chem. Soc. 2004,
126, 4522-4523. (DOI)
30. P. L. Holland, "Nitrogen Fixation," In Comprehensive Coordination Chemistry 2 (McCleverty, J., Meyer, T. J., Eds.); Vol. 8; Elsevier: Oxford, 2004, pp. 569-599.
29. J. M. Smith, R. J. Lachicotte, P. L. Holland*, "N=N Bond Cleavage by a Low-Coordinate Iron(II) Hydride Complex," J. Am. Chem. Soc. 2003, 125, 15752-15753. (PDF)
28. N. A. Eckert, E. M. Bones, R. J. Lachicotte, P. L. Holland*, "Nickel Complexes of a Bulky β-Diketiminate Ligand," Inorg. Chem. 2003, 42, 1720-1725. (PDF)
27. B. A. Jazdzewski, A. M. Reynolds, P. L. Holland, V. G. Young, S. Kaderli, A. D. Zuberbuhler*, W. B. Tolman*, "Copper(I)-phenolate complexes as models of the reduced active site of galactose oxidase: synthesis, characterization, and O2 reactivity," J. Biol. Inorg. Chem. 2003, 8, 381-393.(online)
26. J. Vela, J. M. Smith, R. J. Lachicotte, P. L. Holland*, "Alkyl group isomerisation in three-coordinate iron(II) complexes," Chem. Commun. 2002, 2886-2887.(PDF)
25. P. L. Holland*, T. R. Cundari*, L. L. Perez, N. A. Eckert, R. J. Lachicotte, Electronically Unsaturated Three-Coordinate Chloride and Methyl Complexes of Iron, Cobalt, and Nickel," J. Am. Chem. Soc. 2002, 124, 14416-14424. (PDF)
24. D. J. E. Spencer, A. M. Reynolds, P. L. Holland, B. A. Jazdzewski, C. D. Toia, L. Le Pape, S. Yokota, Y. Tachi, S. Itoh*, W. B. Tolman*, "Copper Chemistry of β-Diketiminate Ligands: Monomer/Dimer Equilibria and a New Class of Bis(μ-oxo)dicopper Compounds," Inorg. Chem. 2002, 41, 6307-6321 . (PDF)
23. J. M. Smith, R. J. Lachicotte, P. L. Holland*, "Three-coordinate, 12-electron organometallic complexes of iron(II): synthesis and insertion of CO to give square pyramidal complexes," Organometallics 2002, 21, 4808-4814. (PDF)
22. D. J. E. Spencer, N. W. Aboelella, A. M. Reynolds, P. L. Holland, W. B. Tolman*, "Diketiminate Ligand Backbone Structural Effects on Cu(I)/O2 Reactivity: Unique Copper-Superoxo and Bis(μ-oxo) Complexes," J. Am. Chem. Soc. 2002, 124, 2108-2109. (PDF)
21. H. Andres, E. M. Bominaar, J. M. Smith, N. A. Eckert, P. L. Holland*, E. Münck*, "Planar Three-Coordinate High-Spin Fe(II) Complexes with Large Orbital Angular Momentum: Mössbauer, Electron Paramagnetic Resonance, and Electronic Structure Studies," J. Am. Chem. Soc. 2002, 124, 3012-3025. (PDF)
20. A. Chowdhury, L. A. Peteanu*, P. L. Holland, W. B. Tolman, "The Electronic Properties of a Model Active Site for Blue Copper Proteins as Probed by Stark Spectroscopy," J. Phys. Chem. B 2002, 106, 3007-3012. (PDF)
19. B. A. Jazdzewski, P. L. Holland, M. Pink, V. G. Young, Jr., D. J. E. Spencer, W. B. Tolman*, "Three-Coordinate Copper(II)-Phenolate Complexes," Inorg. Chem. 2001, 40, 6097-6107. (PDF)
18. J. M. Smith, R. J. Lachicotte, K. A. Pittard, T. R. Cundari*, G. Lukat-Rodgers, K. R. Rodgers, P. L. Holland*, "Stepwise Reduction of N-N Bond Order by a Low-Coordinate Iron Complex," J. Am. Chem. Soc. 2001, 123, 9222-9223. (PDF)
17. J. M. Smith, R. J. Lachicotte, P. L. Holland*, "Tuning Metal Coordination Number by Ancillary Ligand Steric Effects: Synthesis of a Three-Coordinate Iron(II) Complex," Chem. Commun. 2001, 1542-1543. (PDF)
16. D. W. Randall, S. DeBeer George, P. L. Holland, B. Hedman, K. O. Hodgson, W. B. Tolman*, E. I. Solomon*, "Spectroscopic and Electronic Structure Studies of Blue Copper Model Complexes. 2. Comparison of 3- and 4-Coordinate Cu(II) Thiolate Complexes and Fungal Laccase," J. Am. Chem. Soc. 2000, 122, 11632-11648. (PDF)
15. E. Meggers*, P. L. Holland, W. B. Tolman, F. E. Romesberg*, P. G. Schultz*, "A Novel Copper-Mediated DNA Base Pair," J. Am. Chem. Soc. 2000, 122, 10714-10715. (PDF)
14. B. M. T. Lam, J. A. Halfen, V. G. Young, Jr., J. R. Hagadorn, P. L. Holland, A. Lledós, L. Cucurull-Sánchez, J. J. Novoa, S. Alvarez*, W. B. Tolman*, "Ligand Macrocycle Structural Effects on Copper-Dioxygen Reactivity," Inorg. Chem. 2000, 39, 4059-4072. (PDF))
13. P. L. Holland, W. B. Tolman*, "A Structural Model of the Type 1 Copper Protein Active Site: N2S(thiolate)S(thioether) Ligation in a Cu(II) Complex," J. Am. Chem. Soc. 2000, 122, 6331-6332. (PDF))
12. P. L. Holland, C. J. Cramer*, E. C. Wilkinson, S. Mahapatra, K. R. Rodgers, S. Itoh, M. Taki, S. Fukuzumi, L. Que, Jr.*, W. B. Tolman*, "Resonance Raman Spectroscopy as a Probe of the Bis(μ-oxo)dicopper Core," J. Am. Chem. Soc. 2000, 122, 792-802. (PDF)
11. S. Itoh*, M. Taki, H. Nakao, P. L. Holland, W. B. Tolman, L. Que, Jr., S. Fukuzumi*, "Aliphatic Hydroxylation by Bis(μ-oxo)dicopper Complex," Angew. Chem. Int. Ed. 2000, 39, 398-400. (PDF)
10. P. L. Holland, W. B. Tolman*, "Three-Coordinate Cu(II) Complexes: Structural Models of Trigonal-Planar Type 1 Copper Protein Active Sites," J. Am. Chem. Soc. 1999, 121, 7270-7271. (PDF)
9. P. L. Holland, W. B. Tolman*, "Dioxygen Activation by Copper Sites: Stability and Reactivity of Peroxo- and Bis(μ-oxo)dicopper Cores," Coord. Chem. Rev. 1999, 190-192, 855-869. (PDF)
8. J. Cahoy, P. L. Holland, W. B. Tolman*, "Experimental Studies of the Interconversion of Peroxo- and Bis(μ-oxo)dicopper Complexes," Inorg. Chem. 1999, 38, 2161-2168. (PDF)
7. P. L. Holland, K. R. Rodgers, W. B. Tolman*, "Is the Bis(μ-oxo)dicopper Core Capable of Hydroxylating an Arene?" Angew. Chem. Int. Ed. 1999, 38, 1139-1142. (PDF)
6. P. L. Holland*, R. A. Andersen, R. G. Bergman, "Application of the E-C Approach to Understanding the Bond Energies of Late-Metal Amido, Aryloxo and Alkoxo Complexes: An Alternative to pπ/dπ Repulsion," Comments Inorg. Chem. 1999, 21, 115-129. (PDF)
5. P. L. Holland, R. A. Andersen*, R. G. Bergman*, "Cyclopentadienyl and Imide Ligand Transfer From Zirconium to Iridium: Can Early-Metal Imido Compounds Be Used as Imide Transfer Reagents?" Organometallics 1998, 17, 433-437. (PDF)
4. J. T. Golden, T. H. Peterson, P. L. Holland, R. G. Bergman*, R. A. Andersen*, "Adduct Formation and Single and Double Deprotonation of Cp*(PMe3)Ir(H)2 with Main Group Metal Alkyls and Aryls: Synthesis and Structure of Three Novel Ir-Al and Ir-Mg Heterobimetallics," J. Am. Chem. Soc. 1998, 120, 223-224. (PDF)
3. P. L. Holland, R. A. Andersen*, R. G. Bergman*, J. Huang, S. P. Nolan, "Monomeric Cyclopentadienylnickel Methoxo and Amido Complexes: Synthesis, Characterization, Reactivity, and Use for Exploring the Relationship Between H-X and M-X Bond Energies," J. Am. Chem. Soc. 1997, 119, 12800-12814. (PDF)
2. P. L. Holland, M. E. Smith, R. A. Andersen*, R. G. Bergman, "X-ray Crystal Structures of Cp*Ni(PEt3)X. Understanding Distortions and Trans Influences in Cyclopentadienyl Complexes," J. Am. Chem. Soc. 1997, 119, 12815-12823. (PDF)
1. P. L. Holland, R. A. Andersen*, R. G. Bergman*, "Synthesis, Characterization, and Reactivity of Dimeric Amidonickel Complexes," J. Am. Chem. Soc. 1996, 118, 1092-1104. (PDF)